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Karpinski, A., Berson, S., Terrisse, H., Mancini-Le Granvalet, M., Guillerez, S., Brohan, L. & Richard-Plouet, M. (2013) Anatase colloidal solutions suitable for inkjet printing: Enhancing lifetime of hybrid organic solar cells. Sol. Energy Mater. Sol. Cells, 116 27–33. 
Added by: Laurent Cournède (2016-03-10 21:23:30)
Type de référence: Article
DOI: 10.1016/j.solmat.2013.04.006
Numéro d'identification (ISBN etc.): 0927-0248
Clé BibTeX: Karpinski2013
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Catégories: CESES
Mots-clés: Anatase colloidal solution for printing, Hybrid organic solar cell, Inverted polymer solar cell, layer, polymer photovoltaic cells, Solar cell stability, Titanium sub-oxide, titanium-oxide, Water
Créateurs: Berson, Brohan, Guillerez, Karpinski, Mancini-Le Granvalet, Richard-Plouet, Terrisse
Collection: Sol. Energy Mater. Sol. Cells
Consultations : 11/437
Indice de consultation : 2%
Indice de popularité : 0.5%
Résumé     
We describe a one-pot chemical synthesis to produce TiO2-x(OH)(2x) colloidal solutions that are suitable to be deposited, at 150 degrees C only, as interfacial electron transporting layer, in inverted organic solar cells. The crystallized nanoparticles were synthesized from the hydrolysis of [Ti8O12(H2O)(24)]Cl8HCl center dot 7H(2)O in organic solvent, using solvothermal method at 120 degrees C. The UV-illumination of TiO2 colloidal solutions, before the deposition process, was found to improve the initial performance of solar cells. Compared to the usual sol-gel TiOx layer, no kink shape of the I/V curve is observed, indicating the good quality of the interfacial contact with the P3HT:PCBM blend of polymer. Additionally it is worth noting the significant improvement of the solar cells stability, characterized by a loss of power conversion efficiency limited to 17\% after 6500 h over continuous AM 1.5 illumination. (C) 2013 Elsevier B.V. All rights reserved.
Added by: Laurent Cournède  
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