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De, S., Mouchaham, G., Liu, F., Affram, M., Abeykoon, B., Guillou, N., Jeanneau, E., Greneche, J.-M., Khrouz, L., Martineau-Corcos, C., Boudjema, L., Salles, F., Salcedo-Abraira, P., Valente, G., Souto, M., Fateeva, A. & Devic, T. (2023) Expanding the horizons of porphyrin metal–organic frameworks via catecholate coordination: exploring structural diversity, material stability and redox properties. J. Mater. Chem. A, 11 25465–25483.
Added by: Richard Baschera (2023-12-08 07:42:54) |
| Type de référence: Article DOI: 10.1039/D3TA04490D Numéro d'identification (ISBN etc.): 2050-7496 Clé BibTeX: De2023 Voir tous les détails bibliographiques  |
Catégories: INTERNATIONAL, ST2E Créateurs: Abeykoon, Affram, Boudjema, De, Devic, Fateeva, Greneche, Guillou, Jeanneau, Khrouz, Liu, Martineau-Corcos, Mouchaham, Salcedo-Abraira, Salles, Souto, Valente Collection: J. Mater. Chem. A |
Consultations : 1/90
Indice de consultation : 13% Indice de popularité : 3.25% |
| Liens URLs https://pubs.rsc.o ... 2023/ta/d3ta04490d |
| Résumé |
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Porphyrin based Metal–Organic Frameworks (MOFs) have generated high interest because of their unique combination of light absorption, electron transfer and guest adsorption/desorption properties. In this study, we expand the range of available MOF materials by focusing on the seldom studied porphyrin ligand H10TcatPP, functionalized with tetracatecholate coordinating groups. A systematic evaluation of its reactivity with M(III) cations (Al, Fe, and In) led to the synthesis and isolation of three novel MOF phases. Through a comprehensive characterization approach involving single crystal and powder synchrotron X-ray diffraction (XRD) in combination with the local information gained from spectroscopic techniques, we elucidated the structural features of the solids, which are all based on different inorganic secondary building units (SBUs). All the synthesized MOFs demonstrate an accessible porosity, with one of them presenting mesopores and the highest reported surface area to date for a porphyrin catecholate MOF ({>}2000 m2 g−1). Eventually, the redox activity of these solids was investigated in a half-cell vs. Li with the aim of evaluating their potential as electrode positive materials for electrochemical energy storage. One of the solids displayed reversibility during cycling at a rather high potential (∼3.4 V vs. Li+/Li), confirming the interest of redox active phenolate ligands for applications involving electron transfer. Our findings expand the library of porphyrin-based MOFs and highlight the potential of phenolate ligands for advancing the field of MOFs for energy storage materials.
Added by: Richard Baschera |
| Notes |
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Publisher: The Royal Society of Chemistry
Added by: Richard Baschera |