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Le Tonquesse, S., Bouteiller, H., Matsushita, Y., Cortez, A., Bux, S. K., Imasato, K., Ohta, M., Halet, J.-F., Mori, T., Gascoin, F. & Berthebaud, D. (2023) Enhanced High-Temperature Thermoelectric Performance of Yb4Sb3 via Ce/Bi Co-doping and Metallic Contact Deposition for Device Integration. ACS Appl. Energy Mater. 6 10088–10097.
Added by: Richard Baschera (2023-11-22 08:50:17) Last edited by: Richard Baschera (2023-11-22 08:58:59) |
| Type de référence: Article DOI: 10.1021/acsaem.3c01693 Clé BibTeX: LeTonquesse2023 Voir tous les détails bibliographiques  |
Catégories: INTERNATIONAL, MIOPS Créateurs: Berthebaud, Bouteiller, Bux, Cortez, Gascoin, Halet, Imasato, Le Tonquesse, Matsushita, Mori, Ohta Collection: ACS Appl. Energy Mater. |
Consultations : 1/281
Indice de consultation : 36% Indice de popularité : 9% |
| Liens URLs https://doi.org/10.1021/acsaem.3c01693 |
| Résumé |
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Thermoelectrics (TE) for very high temperatures ({>}800 K) have numerous potential applications in heavy industry and space exploration. This article focuses on the compound Yb4Sb3 which is a promising p-type counterpart to the structurally related and high-performance n-type RE3Te4 (RE = Nd, La, Pr) for the fabrication of high-temperature TE modules. A quick and efficient method for synthesizing pure and fully dense Yb4Sb3 samples was developed and optimized using high-energy ball milling followed by reactive spark plasma sintering. The technique was utilized to produce a series of doubly doped CexYb4–xBi0.2Sb2.8 compounds. X-ray diffraction and scanning electron microscopy (SEM) were employed to establish the solubility limit of Ce, which was determined to be x = 0.4. TE properties of Yb4Sb3 and Ce0.4Yb3.6Bi0.2Sb2.8 were measured up to 1273 K, revealing that the doping strategy was effective in reducing the charge carrier concentration and thermal conductivity. This led to a significant increase in the TE figure-of-merit zT from 0.2 to 0.4 at 1273 K. In addition, screening of metallic contacts was conducted for the development of a thermoelectric module with Yb4Sb3. The results showed that two robust TE legs with Ni and Cu contacts were successfully produced through spark plasma sintering. The measured electric contact resistances were very promising, with average values of 2 and 1 μΩ cm2 for Ni and Cu contacts, respectively.
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Publisher: American Chemical Society
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