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Wang, Y., Nisbet, M. L., Kamp, K. R., Hiralal, E., Gautier, R., Halasyamani, S. P. & Poeppelmeier, K. R. (2023) Beyond pi-pi Stacking: Understanding Inversion Symmetry Breaking in Crystalline Racemates. Journal of the American Chemical Society, 145 16879–16888.
Added by: Richard Baschera (2023-08-17 13:13:20) Last edited by: Richard Baschera (2023-08-17 13:32:32) |
| Type de référence: Article DOI: 10.1021/jacs.3c05380 Numéro d'identification (ISBN etc.): 0002-7863 Clé BibTeX: Wang2023 Voir tous les détails bibliographiques  |
Catégories: INTERNATIONAL, MIOPS Créateurs: Gautier, Halasyamani, Hiralal, Kamp, Nisbet, Poeppelmeier, Wang Collection: Journal of the American Chemical Society |
Consultations : 1/93
Indice de consultation : 7% Indice de popularité : 1.75% |
| Liens URLs https://doi.org/10.1021/jacs.3c05380 |
| Résumé |
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The design of noncentrosymmetric (NCS) solid state materials, specifically how to break inversion symmetry between enantiomers, has intrigued chemists, physicists, and materials scientists for many years. Because the chemical complexity of molecular racemic building units is so varied, targeting these materials is poorly understood. Previously, three isostructural racemic compounds with a formula of [Cu(H2O)(bpy)2]2[MF6]2·2H2O (bpy = 2,2’=bipyridine; M = Ti, Zr, Hf) were shown to crystallize in the NCS space group Pna21, of polar, achiral crystal class mm2. In this work, we synthesized five new racemic compounds with the formula [Cu(H2O)(dmbpy)2]2[MF6]2·xH2O (dmbpy = 4,4′/5,5′-dimethyl-2,2′-bipyridine; M = Ti, Zr, Hf). Single crystal X-ray diffraction reveals that the five newly synthesized compounds feature equimolar combinations of Δ- and Λ-Cu(dmbpy)2(H2O)2+ complexes that are assembled into packing motifs similar to those found in the reported NCS structure but all crystallize in centrosymmetric (CS) space groups. Seven structural descriptors were created to analyze the intermolecular interactions on the assembly of Cu racemates in the CS and NCS structures. The structural analysis reveals that in the CS structures, the inversion center results from parallel heterochiral π–π stacking interactions between adjacent Cu racemates regardless of cation geometries, hydrogen bonding networks, or interlayer architectures, whereas in the NCS structure, nonparallel heterochiral π–π interactions between the adjacent Cu racemates preclude an inversion center. The parallel heterochiral π–π interactions in the CS structures can be rationalized by the restrained geometries of the methyl-substituted ligands. This work demonstrates that the introduction of nonparallel stacking can suppress the formation of an inversion center for an NCS racemate. A conceptual framework and practical approach linking the absence of inversion symmetry in racemates is presented for all NCS crystal classes.
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Publisher: American Chemical Society
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