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Fateeva, A., Guillou, N. & Devic, T. (2023) Insightful contribution of Fe-57 Mossbauer spectrometry (and of Jean-Marc Greneche) to the field of iron metal organic frameworks. Journal of Materials Research, 38 1007–1018.
Added by: Richard Baschera (2022-11-04 14:35:25) Last edited by: Richard Baschera (2023-11-22 17:44:41) |
| Type de référence: Article DOI: 10.1557/s43578-022-00772-2 Numéro d'identification (ISBN etc.): 0884-2914 Clé BibTeX: Fateeva2023 Voir tous les détails bibliographiques  |
Catégories: ST2E Créateurs: Devic, Fateeva, Guillou Collection: Journal of Materials Research |
Consultations : 1/242
Indice de consultation : 9% Indice de popularité : 2.25% |
| Résumé |
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We describe here the relevant input of Mossbauer spectrometry for the investigation of porous coordination polymers, or metal organic frameworks (MOFs) containing iron cations. We specifically focus on selected examples taken from the long-lasting collaboration between the physicist Jean-Marc Greneche and French MOF chemists issued from the group of late Gerard Ferey. After a brief historical recall, we discuss the expected inputs of Mossbauer spectrometry for chemists working on the synthesis and characterization of new MOFs materials. Two examples are thoroughly described: a series of flexible MOFs presenting the MIL-53 topology, and MOFs based on porphyrin ligands. Through these examples, we will show how the combination of characterization tools (notably X-ray diffraction and Mossbauer spectrometry) is mandatory to achieve a thorough and accurate description of these complex porous hybrid materials and their properties.
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