Sasaki, S., Steciuk, G., Guillot-Deudon, C., Caldes, M. T., Braems, I., Janod, E., Corraze, B., Jobic, S. & Cario, L. (2021) Solvothermal and mechanochemical intercalation of Cu into La2O2S2 enabled by the redox reactivity of (S2)2− pairs. Dalton Trans. 50 12419–12423.
Added by: Richard Baschera (2021-10-22 16:10:52) Last edited by: Richard Baschera (2021-10-22 16:12:11) |
Type de référence: Article DOI: 10.1039/D1DT01976G Numéro d'identification (ISBN etc.): 1477-9234 Clé BibTeX: Sasaki2021a Voir tous les détails bibliographiques |
Catégories: ID2M, INTERNATIONAL, MIOPS, PMN Créateurs: Braems, Caldes, Cario, Corraze, Guillot-Deudon, Janod, Jobic, Sasaki, Steciuk Collection: Dalton Trans. |
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Liens URLs http://pubs.rsc.or ... 2021/dt/d1dt01976g |
Résumé |
Intercalation of Cu into layered polychalcogenide La2O2S2 was demonstrated to be viable both under solvothermal conditions at 200 °C and mechanical ball milling at ambient temperature. This result evidences the soft-chemical nature of metal intercalation into layered polychalcogenides driven by the redox reactivity of anion–anion bonds.
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Publisher: The Royal Society of Chemistry
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