 |
 |
|
Kabbour, H., Sayede, A., Saitzek, S., Lefevre, G., Cario, L., Trentesaux, M. & Roussel, P. (2020) Structure of the water-splitting photocatalyst oxysulfide alpha-LaOInS2 and ab initio prediction of new polymorphs. Chem. Commun. 56 1645–1648.
Added by: Richard Baschera (2020-02-28 09:15:43) Last edited by: Richard Baschera (2020-02-28 09:16:52) |
| Type de référence: Article DOI: 10.1039/c9cc09797j Numéro d'identification (ISBN etc.): 1359-7345 Clé BibTeX: Kabbour2020 Voir tous les détails bibliographiques  |
Catégories: PMN Mots-clés: chemistry, indium, inorganic-compounds, layered oxychalcogenides, magnetic-properties, reduction Créateurs: Cario, Kabbour, Lefevre, Roussel, Saitzek, Sayede, Trentesaux Collection: Chem. Commun. |
Consultations : 1/366
Indice de consultation : 5% Indice de popularité : 1.25% |
| Résumé |
|
We unveil the structure and investigate the visible light water-splitting of the photocatalyst alpha-LaOInS2, the second polymorph in this composition. This remarkable oxysulfide exhibits rare mixed anion InS5O octahedra leading to both O-2p and S-3p hybridized with indium states in the vicinity of the Fermi level. Ab initio structure prediction shows the stability of such heteroleptic environments and points to other hypothetical polymorphs.
|