Markova, I., Milanova, V., Petrov, T., Denev, I. & Chauvet, O. (2015) New Porous Nanocomposite Materials for Electrochemical Power Sources. Proceedings of the 4th International Conference on Materials and Applications for Sensors and Transducers, Key Engineering Materials 129–132.
Added by: Richard Baschera (2020-01-28 16:21:00) Last edited by: Richard Baschera (2020-01-28 16:34:59)
|Type de référence: Article
Clé BibTeX: Markova2015
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|Catégories: INTERNATIONAL, PMN
Mots-clés: Borohydride Reduction, Cyclic voltammetry, Intermetallic (Cu-Sn) Nanoparticles, Li-ion battery, nanocomposites, Support, template synthesis
Créateurs: Chauvet, Denev, Markova, Milanova, Petrov
Éditeur: Trans Tech Publications Ltd
Collection: Proceedings of the 4th International Conference on Materials and Applications for Sensors and Transducers
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Intermetallic (Cu-Sn) nanoparticles are synthesized through a borohydride reduction with NaBH4 in a mixture of aqueous solutions of CuCl2.2H2O and SnCl2.2H2O at mass ratio Cu:Sn = 3:2 applying a template technique with a support such as carbon foam. The ratio is chosen in accordance with the Cu-Sn binary system phase diagram. The reductive precipitation is carried out at room temperature and atmospheric pressure. Porous nanocomposites are obtained and studied by scanning and transmission electron microscopy (SEM/TEM), and X-ray diffraction (XRD) analysis. The electrochemical behavior of the synthesized Cu-Sn alloy and the C-based composites (С-foam/Cu-Sn alloy) as positive electrodes is also investigated in a Li-ion battery) using a computer controlled laboratory cycling equipment BA500 Series Battery Analyzer.