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Llewellyn, P. L., Bourrelly, S., Vagner, C., Heymans, N., Leclerc, H., Ghoufi, A., Bazin, P., Vimont, A., Daturi, M., Devic, T., Serre, C., De Weireld, G. & Maurin, G. (2013) Evaluation of MIL-47(V) for CO2-Related Applications. JOURNAL OF PHYSICAL CHEMISTRY C, 117 962–970.
Added by: Richard Baschera (2017-03-01 08:48:22) |
| Type de référence: Article DOI: {10.1021/jp308525k} Numéro d'identification (ISBN etc.): {1932-7447} Clé BibTeX: Llewellyn{2013} Voir tous les détails bibliographiques  |
Catégories: HORSIMN Créateurs: Bazin, Bourrelly, Daturi, De Weireld, Devic, Ghoufi, Heymans, Leclerc, Llewellyn, Maurin, Serre, Vagner, Vimont Collection: {JOURNAL OF PHYSICAL CHEMISTRY C} |
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{Carbon dioxide and methane adsorption has been carried out up to 50 bar on the MIL-47(V) metal-organic framework (MOF) at 303 K. The so-obtained performance has been compared with other well-known MOFs, an activated carbon, and the zeolite NaY both in amount and volume adsorbed scales. In the latter scale, which would be of interest for real applications, the MIL-47(V) shows promising results similar to those of Cu-3(BTC)(2) or HKUST-1. Operando Infrared experiments have been employed to characterize the strength of the interactions in play. Finally, the CO2/CH4 separation properties have been further predicted using a combination of macroscopic and microscopic modeling approaches. This body of results suggests that this material should be considered for gas separation.}
Added by: Richard Baschera |