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Yot, P. G., Yang, K., Ragon, F., Dmitriev, V., Devic, T., Horcajada, P., Serre, C. & Maurin, G. (2016) Exploration of the mechanical behavior of metal organic frameworks UiO-66(Zr) and MIL-125(Ti) and their NH2 functionalized versions. DALTON TRANSACTIONS, 45 4283–4288. 
Added by: Richard Baschera (2017-03-01 08:48:21)
Type de référence: Article
DOI: {10.1039/c5dt03621f}
Numéro d'identification (ISBN etc.): {1477-9226}
Clé BibTeX: Yot{2016}a
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Catégories: HORSIMN
Créateurs: Devic, Dmitriev, Horcajada, Maurin, Ragon, Serre, Yang, Yot
Collection: {DALTON TRANSACTIONS}
Consultations : 8/316
Indice de consultation : 2%
Indice de popularité : 0.5%
Résumé     
{The structural behaviour under mechanical stimuli of two metal organic frameworks, UiO-66(Zr) and MIL-125(Ti) and their amino-functionalized derivatives has been investigated by high-pressure powder X-ray diffraction up to 3.5 GPa. All these solids showed a gradual pressure-induced reversible decrease of their crystallinity and UiO-66(Zr)_NH2 material has been revealed as one of the most resilient MOFs reported so far corresponding to a very high bulk modulus. The mechanical behaviors of these MOFs have been correlated to their chemical and geometric features including the metal-oxygen coordination number, the nature of the organic linker, the porosity as well as their crystal density.}
Added by: Richard Baschera  
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