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Yot, P. G., Yang, K., Ragon, F., Dmitriev, V., Devic, T., Horcajada, P., Serre, C. & Maurin, G. (2016) Exploration of the mechanical behavior of metal organic frameworks UiO-66(Zr) and MIL-125(Ti) and their NH2 functionalized versions. DALTON TRANSACTIONS, 45 4283–4288.
Added by: Richard Baschera (2017-03-01 08:48:21) |
| Type de référence: Article DOI: {10.1039/c5dt03621f} Numéro d'identification (ISBN etc.): {1477-9226} Clé BibTeX: Yot{2016}a Voir tous les détails bibliographiques  |
Catégories: HORSIMN Créateurs: Devic, Dmitriev, Horcajada, Maurin, Ragon, Serre, Yang, Yot Collection: {DALTON TRANSACTIONS} |
Consultations : 1/464
Indice de consultation : 4% Indice de popularité : 1% |
| Résumé |
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{The structural behaviour under mechanical stimuli of two metal organic frameworks, UiO-66(Zr) and MIL-125(Ti) and their amino-functionalized derivatives has been investigated by high-pressure powder X-ray diffraction up to 3.5 GPa. All these solids showed a gradual pressure-induced reversible decrease of their crystallinity and UiO-66(Zr)_NH2 material has been revealed as one of the most resilient MOFs reported so far corresponding to a very high bulk modulus. The mechanical behaviors of these MOFs have been correlated to their chemical and geometric features including the metal-oxygen coordination number, the nature of the organic linker, the porosity as well as their crystal density.}
Added by: Richard Baschera |