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de Santana, H., Quillard, S., Fayad, E. & Louarn, G. (2006) In situ UV-vis and Raman spectroscopic studies of the electrochemical behavior of N,N '-diphenyl-1,4-phenylenediamine. Synth. Met. 156 81–85. 
Added by: Florent Boucher (2016-05-12 13:21:38)
Type de référence: Article
DOI: 10.1016/j.synthmet.2005.10.013
Numéro d'identification (ISBN etc.): 0379-6779
Clé BibTeX: deSantana2006a
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Catégories: PMN
Mots-clés: 4-benzoquinonediimine, 4-phenylenediamine, aniline, model-compound, n, N '-diphenyl-1, oligoanilines, oligomers, polyaniline, polymer, Raman spectroscopy, spectroelectrochemistry, vibrational analysis
Créateurs: Fayad, Louarn, Quillard, de Santana
Collection: Synth. Met.
Consultations : 7/866
Indice de consultation : 5%
Indice de popularité : 1.25%
Résumé     
The electrochemical behavior of the N,N'-diphenyl-1,4-phenylenediamine (B3) in acid solution has been investigated by in situ UV-vis and Raman spectroscopies. The electrogenerated species semiquinone form (B3(circle+)) and monoprotonated structure of B3 (B3(+)) have been characterized as the main products of B3 oxidation. The N,N'-diphenyl-1,4-benzoquinonediimine (B2Q1) species has also been characterized in B3 neutral solution and the B3(circle+) proton loss was attributed to proton absence in solution. Finally, a mechanism has been proposed concerning the electron and proton transfer that occurs during the oxidation process. (C) 2005 Elsevier B.V. All rights reserved.
Added by: Florent Boucher  
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