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Djerdj, I., Cao, M., Rocquefelte, X., Cerny, R., Jaglicic, Z., Arcon, D., Potocnik, A., Gozzo, F. & Niederberger, M. (2009) Structural Characterization of a Nanocrystalline Inorganic-Organic Hybrid with Fiberlike Morphology and One-Dimensional Antiferromagnetic Properties. Chem. Mat. 21 3356–3369.
Added by: Laurent Cournède (2016-03-10 21:41:23) |
| Type de référence: Article DOI: 10.1021/cm901345h Numéro d'identification (ISBN etc.): 0897-4756 Clé BibTeX: Djerdj2009 Voir tous les détails bibliographiques  |
Catégories: MIOPS Mots-clés: chemistry, electron-spin-resonance, frameworks, metal-oxide nanoparticles, nanorods, nanostructures, networks, nonaqueous synthesis, optoelectronic devices, routes Créateurs: Arcon, Cao, Cerny, Djerdj, Gozzo, Jaglicic, Niederberger, Potocnik, Rocquefelte Collection: Chem. Mat. |
Consultations : 1/870
Indice de consultation : 6% Indice de popularité : 1.5% |
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{A new nanocrystalline inorganic-organic hybrid compound, VO(C6H5COO)(2) has been synthesized under solvothermal conditions by reacting vanadium(V) oxytriisopropoxide with benzoic acid in toluene. A detailed investigation of the composition, structure and properties Of VO(C6H5COO)(2) using chemical and thermal analysis, synchrotron X-ray powder diffraction, electron microscopy techniques including SEM, TEM and SAED, spectroscopy techniques like XPS, EDX and FTIR, SQUID magnetometry and EPR is carefully described. Due to the low-crystallinity of the final material, its crystal structure has been solved from synchrotron X-ray powder diffraction data by combining a direct space global optimization technique and DFT geometry optimization and subsequently refined by the constraint Rietveld method. The compound crystallizes in the monoclinic system with a = 20.652(3)
Added by: Laurent Cournède |