Jessop, I. A., Zamora, P. P., Diaz, F. R., del Valle, M. A., Leiva, A., Cattin, L., Makha, M. & Bernede, J. C. (2012) New Polymers Based on 2,6-di(thiophen-2-yl) aniline and 2,2 '-(thiophen-2,5-diyl) dianiline Monomers. Preparation, Characterization and Thermal, Optical, Electronic and Photovoltaic Properties. Int. J. Electrochem. Sci. 7 9502–9517.
Added by: Laurent Cournède (2016-03-10 21:28:38) |
Type de référence: Article Numéro d'identification (ISBN etc.): 1452-3981 Clé BibTeX: Jessop2012 Voir tous les détails bibliographiques |
Catégories: CESES Mots-clés: aniline and thiophene derivatives, chemical polymerization, chemical sensors, conducting polymers, copolymer, corrosion protection, cross-coupling reactions, derivatives, devices, doped polyaniline, electrochemical polymerization, halides, photovoltaic devices, polythiophene, Thiophene Créateurs: Bernede, Cattin, Diaz, Jessop, Leiva, Makha, del Valle, Zamora Collection: Int. J. Electrochem. Sci. |
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Résumé |
A new series of polymers, chemically and electrochemically obtained from monomers containing aniline and thiophene moieties, has been prepared. The purpose is to use them as electron donor layers in the fabrication of dual-layer organic solar cells. Both the monomers and the polymers were characterized using techniques such as NMR, FT-IR, cyclic voltammetry, etc. It was found that polymer growth occurred only through aniline unit(s) and not through thiophene unit(s), as might also be expected. Optical and electronic studies revealed that the products displayed properties suitable for use in photovoltaic devices. However, prepared prototypes yields ranged just between 10(-2) and 10(-3).
Added by: Laurent Cournède |