Harel, S., Guillot-Deudon, C., Choubrac, L., Hamon, J. & Lafond, A. (2014) Surface composition deviation of Cu2ZnSnS4 derivative powdered samples. Appl. Surf. Sci. 303 107–110.
Added by: Laurent Cournède (2016-03-10 21:01:56) |
Type de référence: Article DOI: 10.1016/j.apsusc.2014.02.096 Numéro d'identification (ISBN etc.): 0169-4332 Clé BibTeX: Harel2014 Voir tous les détails bibliographiques |
Catégories: CESES Mots-clés: cells, cu depletion, Cu-depletion, cu2znsns4, czts, kesterite, photoemission, Solar cell, Surface composition, thin-films, X-ray photoelectron spectroscopy, XPS Créateurs: Choubrac, Guillot-Deudon, Hamon, Harel, Lafond Collection: Appl. Surf. Sci. |
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Résumé |
Powdered samples of Cu2ZnSnS4 derivatives prepared through a solid-state route were investigated by both bulk (electron dispersive X-ray spectroscopy) and surface-sensitive (X-ray photoelectron spectroscopy) methods. We observe a deviation in composition between the surface and the bulk for all non-stoichiometric samples (both Cu-poor and Cu-rich). This behavior has already been observed for slightly Cu-poor CZTS thin films and is reminiscent of that of CIGSe compounds. (C) 2014 Elsevier B.V. All rights reserved.
Added by: Laurent Cournède |