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Chemek, M., Khlaifia, D., Massuyeau, F., Duvail, J. L., Faulques, E., Wery, J. & Alimi, K. (2014) A copolymer of PVK and P3HT and its nanocomposite with single-walled carbon nanotubes. Synth. Met. 197 246–251.
Added by: Laurent Cournède (2016-03-10 21:01:54) |
| Type de référence: Article DOI: 10.1016/j.synthmet.2014.09.004 Numéro d'identification (ISBN etc.): 0379-6779 Clé BibTeX: Chemek2014 Voir tous les détails bibliographiques  |
Catégories: PMN Mots-clés: composite films, conjugated polymers, optical-properties, poly(3-alkylthiophenes), poly(3-hexylthiophene), Poly(3-hexylthiophene) (P3HT), poly(n-vinylcarbazole), Poly(N-vinylcarbazole) (PVK), polythiophenes, Single walled carbon nanotubes, state, Transient photoluminescence spectroscopy, vinylcarbazole Créateurs: Alimi, Chemek, Duvail, Faulques, Khlaifia, Massuyeau, Wery Collection: Synth. Met. |
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| Résumé |
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A new copolymer based on poly(N-vinylcarbazole) (PVK) and poly(3-hexylthiophene) (P3HT) denoted PVK-HeT was synthesized by chemical oxidative way. Spectroscopic investigations based on infrared analysis show the formation of bicarbazilium units by chemical inter or intra cross-linking of carbazole units altogether with the formation of P3HT main chain. Photophysical properties of the synthetized copolymer were investigated by means of steady-state and time-resolved photoluminescence measurements and compared to those of standard P3HT. Compared to pristine P3HT, fluorescence spectra of PVK-HeT present a blue shift, as well as an enhancement of the quantum yield. The incorporation of single walled carbon nanotubes (SWNTs) into the PVK-HeT matrix induces a deep modification of the optical properties showing an intensive interaction of the pi-system with SWNTs accompanied with charge transfer between the prepared copolymer and carbon nanotubes in solution. (C) 2014 Elsevier B.V. All rights reserved.
Added by: Laurent Cournède |