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Amela-Cortes, M., Molard, Y., Paofai, S., Desert, A., Duvail, J.-L., Naumov, N. G. & Cordier, S. (2016) Versatility of the ionic assembling method to design highly luminescent PMMA nanocomposites containing [M(6)Q(8)(i) L-6(a)](n-) octahedral nano-building blocks. Dalton Trans. 45 237–245. 
Added by: Laurent Cournède (2016-03-10 20:44:50)
Type de référence: Article
DOI: 10.1039/c5dt03734d
Numéro d'identification (ISBN etc.): 1477-9226
Clé BibTeX: AmelaCortes2016
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Catégories: PMN
Mots-clés: chalcogenide clusters, halide clusters, hexanuclear molybdenum, hexarhenium(iii) clusters, Hybrid materials, photophysical properties, polymers, solution chemistry, transition-metal clusters, zno quantum dots
Créateurs: Amela-Cortes, Cordier, Desert, Duvail, Molard, Naumov, Paofai
Collection: Dalton Trans.
Consultations : 6/486
Indice de consultation : 2%
Indice de popularité : 0.5%
Résumé     
New luminescent poly(methylmethacrylate) (PMMA) nanocomposites with high content of different hexanuclear octahedral cluster building blocks, namely [Mo6I8(C2F5COO6)](2-), [Re6Se8(CN)(6)](4-) and [W6Cl14](2-) have been prepared by free-radical polymerisation. To do so, cluster complexes bearing a polymerisable ammonium counter-cation have been synthesised. In this way, we demonstrate that ionic assembling is a powerful tool to functionalise easily any type of anionic cluster units to be introduced in a PMMA organic matrix. All samples remain homogeneous, stable during several months, and retain the luminescence properties of the cluster precursor.
Added by: Laurent Cournède  
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