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Choubrac, L., Lafond, A., Paris, M., Guillot-Deudon, C. & Jobic, S. (2015) The stability domain of the selenide kesterite photovoltaic materials and NMR investigation of the Cu/Zn disorder in Cu2ZnSnSe4 (CZTSe). Phys. Chem. Chem. Phys. 17 15088–15092. 
Added by: Laurent Cournède (2016-03-10 18:36:42)
Type de référence: Article
DOI: 10.1039/c5cp01709b
Numéro d'identification (ISBN etc.): 1463-9076
Clé BibTeX: Choubrac2015
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Catégories: MIOPS
Mots-clés: poor, solar-cells, spectroscopy, system
Créateurs: Choubrac, Guillot-Deudon, Jobic, Lafond, Paris
Collection: Phys. Chem. Chem. Phys.
Consultations : 1/412
Indice de consultation : 1%
Indice de popularité : 0.25%
Résumé     
Bulk compounds, prepared via the ceramic route, related to Cu2ZnSnSe4 (CZTSe), a material considered for use in photovoltaic devices, were investigated using NMR spectroscopy, electron-probe microanalyses and X-ray diffraction. These materials adopt the kesterite structure regardless of the Cu and Zn contents. It is also shown that the stability domain of the copper-poor quaternary phases is wider for selenide derivatives than for sulphides. Finally, the Cu/Zn disorder level in CZTSe is found to be higher when the samples are quenched, which is reminiscent of the behaviour of the parent sulphide compounds CZTS.
Added by: Laurent Cournède  
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