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Denis, M., Greneche, J.-M., Gautier, N., Poizot, P. & Devic, T. (2022) Deciphering the Thermal and Electrochemical Behaviors of Dual Redox-Active Iron Croconate Violet Coordination Complexes. Inorg. Chem. 61 9308–9317.
Added by: Richard Baschera (2022-07-05 09:18:48) Last edited by: Richard Baschera (2022-07-05 09:22:55) |
| Type de référence: Article DOI: 10.1021/acs.inorgchem.2c01043 Numéro d'identification (ISBN etc.): 0020-1669 Clé BibTeX: Denis2022 Voir tous les détails bibliographiques  |
Catégories: IMN, ST2E Créateurs: Denis, Devic, Gautier, Greneche, Poizot Collection: Inorg. Chem. |
Consultations : 1/263
Indice de consultation : 8% Indice de popularité : 2% |
| Liens URLs https://doi.org/10 ... .inorgchem.2c01043 |
| Résumé |
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Interest in coordination compounds based on non-innocent ligands (NILs) for electrochemical energy storage has risen in the last few years. We have focused our attention on an overlooked redox active linker, croconate violet, which has not yet been addressed in this field although closely related to standard NILs such as catecholate and tetracyanoquinodimethane. Two anionic complexes consisting of Fe(II) and croconate violet (−2) with balancing potassium cations were isolated and structurally characterized. By a combination of in situ and ex situ techniques (powder and single-crystal X-ray diffraction, infrared, and 57Fe Mössbauer spectroscopies), we have shown that their dehydration occurs through complex patterns, whose reversibility depends on the initial crystal structure but that the structural rearrangements around the iron cations occur without any oxidation. While electrochemical studies performed in solution clearly show that both the organic and inorganic parts can be reversibly addressed, in the solid state, poor charge storage capacities were initially measured, mainly due to the solubilization of the solids in the electrolyte. By optimizing the formulation of the electrode and the composition of the electrolyte, a capacity of {>}100 mA h g–1 after 10 cycles could be achieved. This suggests that this family of redox active linkers deserves to be investigated for solid-state electrochemical energy storage, although it requires the solving of the issues related to the solubilization of the derived coordination compounds.
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Publisher: American Chemical Society
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