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Colasson, B., Devic, T., Gaubicher, J., Martineau-Corcos, C., Poizot, P. & Sarou-Kanian, V. (2021) Dual Electroactivity in a Covalent Organic Network with Mechanically Interlocked Pillar[5]arenes. Chemistry – A European Journal, 27 9589–9596. 
Added by: Richard Baschera (2021-06-17 07:20:19)   Last edited by: Richard Baschera (2021-09-16 16:33:35)
Type de référence: Article
DOI: https://doi.org/10.1002/chem.202100558
Numéro d'identification (ISBN etc.): 1521-3765
Clé BibTeX: Colasson2021
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Catégories: ST2E
Mots-clés: covalent organic networks, electroactive solid, pillar5arene, rotaxane, viologen
Créateurs: Colasson, Devic, Gaubicher, Martineau-Corcos, Poizot, Sarou-Kanian
Collection: Chemistry – A European Journal
Consultations : 21/71
Indice de consultation : 3%
Indice de popularité : 0.75%
Liens URLs     https://chemistry- ... 002/chem.202100558
Résumé     
The synthesis and characterization of a polyrotaxanated covalent organic network (CON) based on the association between the viologen and pillar[5]arene (P[5]OH) units are reported. The mechanical bond allows for the irreversible insertion of n-type redox centers (P[5]OH macrocycles) within a pristine structure based on p-type viologen redox centers. Both redox units are active on a narrow potential range and, in water, the presence of P[5]OH greatly increases the electroactivity of the material.
  
Notes     
_eprint: https://chemistry-europe.onlinelibrary.wiley.com/doi/pdf/10.1002/chem.202100558
  
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