IMN

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Benito, Q., Desboeufs, N., Fargues, A., Garcia, A., Massuyeau, F., Martineau-Corcos, C., Devic, T. & Perruchas, S. (2020) A photoactive copper iodide phosphine-based coordination polymer. New J. Chem. 44 19850–19857. 
Added by: Richard Baschera (2021-01-11 08:11:07)   Last edited by: Richard Baschera (2021-01-11 08:45:09)
Type de référence: Article
DOI: 10.1039/D0NJ04486E
Numéro d'identification (ISBN etc.): 1144-0546, 1369-9261
Clé BibTeX: Benito2020
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Catégories: IMN, MIOPS, ST2E
Créateurs: Benito, Desboeufs, Devic, Fargues, Garcia, Martineau-Corcos, Massuyeau, Perruchas
Collection: New J. Chem.
Consultations : 14/229
Indice de consultation : 5%
Indice de popularité : 1.25%
Liens URLs     http://xlink.rsc.org/?DOI=D0NJ04486E
Résumé     
Coordination of the polymetallic [Cu 4 I 4 ] center by phenyl-based-diphosphine ligands results in a coordination polymer exhibiting luminescence thermochromic properties. , A coordination polymer based on the polymetallic [Cu 4 I 4 ] center was synthesized by coordination with a phenyl-based-diphosphine ligand. The structure of this solid formulated as [Cu 4 I 4 (Ph 2 P(C 6 H 4 ) 2 PPh 2 ) 2 ] n , although crystalline, could not be completely resolved using powder X Ray diffraction analysis. Nevertheless, combining different characterization techniques, in particular 63 Cu and 31 P solid-state NMR analyses, provided insights into the polymeric structure. This coordination polymer appears to be of high dimensionality with possible interpenetrated networks, resulting in low porosity. Photoluminescence characterization revealed that the original luminescence thermochromic properties could be ascribed to the photoactive cluster unit.
  
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