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Blumentritt, F., Latouche, C., Morizet, Y., Caldes, M.-T., Jobic, S. & Fritsch, E. (2020) Unravelling the Origin of the Yellow-Orange Luminescence in Natural and Synthetic Scapolites. Journal of Physical Chemistry Letters, 11 4591–4596.
Added by: Richard Baschera (2020-11-24 15:33:50) Last edited by: Richard Baschera (2020-11-24 15:36:05) |
| Type de référence: Article DOI: 10.1021/acs.jpclett.0c00712 Numéro d'identification (ISBN etc.): 1948-7185 Clé BibTeX: Blumentritt2020 Voir tous les détails bibliographiques  |
Catégories: MIOPS Créateurs: Blumentritt, Caldes, Fritsch, Jobic, Latouche, Morizet Collection: Journal of Physical Chemistry Letters |
Consultations : 1/522
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After decades of speculation without material proof, the yellow-orange luminescence of scapolite is definitely assigned to (S-2)(-) activators trapped in [Na-4] square cages. Synthetic sulfur-doped scapolites confirm the implication of sulfur species in luminescence. Formally, the emission and excitation spectra of various polysulfide species were calculated. The excellent match between theory and experiments for (S-2)(-) dimers provides definitive proof that it is the cause of the yellow-orange luminescence in scapolite.
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WOS:000548027700009
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