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Vacher, A., Le Gal, Y., Roisnel, T., Dorcet, V., Devic, T., Barriere, F. & Lorcy, D. (2019) Electronic Communication within Flexible Bisdithiolene Ligands Bridging Molybdenum Centers. Organometallics, 38 4399–4408. 
Added by: Richard Baschera (2019-12-20 09:42:21)   Last edited by: Richard Baschera (2019-12-20 09:44:56)
Type de référence: Article
DOI: 10.1021/acs.organomet.9b00485
Numéro d'identification (ISBN etc.): 0276-7333
Clé BibTeX: Vacher2019a
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Catégories: ST2E
Mots-clés: 1, 3-dithiole-2-thione-4, 5-dithiolate, carbon-disulfide, chemistry, cofactor, complexes, delocalization, dithiolene, interplay, Mo
Créateurs: Barriere, Devic, Dorcet, Le Gal, Lorcy, Roisnel, Vacher
Collection: Organometallics
Consultations : 1/372
Indice de consultation : 5%
Indice de popularité : 1.25%
Bimetallic molybdenum dithiolene complexes involving two flexible ditopic conjugated linkers have been synthesized and characterized by electrochemistry, spectroelectrochemistry, and single crystal X-ray diffraction. The electrochemical investigations evidence that the two metallic bisdithiolene moieties are electronically coupled in the monocationic state. DFT and TDDFT calculations further suggest that the intervalence charge transfer within both monocations is essentially localized on the ligand and can be described as an intraligand charge transfer (ILCT).
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