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Vacher, A., Le Gal, Y., Roisnel, T., Dorcet, V., Devic, T., Barriere, F. & Lorcy, D. (2019) Electronic Communication within Flexible Bisdithiolene Ligands Bridging Molybdenum Centers. Organometallics, 38 4399–4408.
Added by: Richard Baschera (2019-12-20 09:42:21) Last edited by: Richard Baschera (2019-12-20 09:44:56) |
| Type de référence: Article DOI: 10.1021/acs.organomet.9b00485 Numéro d'identification (ISBN etc.): 0276-7333 Clé BibTeX: Vacher2019a Voir tous les détails bibliographiques  |
Catégories: ST2E Mots-clés: 1, 3-dithiole-2-thione-4, 5-dithiolate, carbon-disulfide, chemistry, cofactor, complexes, delocalization, dithiolene, interplay, Mo Créateurs: Barriere, Devic, Dorcet, Le Gal, Lorcy, Roisnel, Vacher Collection: Organometallics |
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Bimetallic molybdenum dithiolene complexes involving two flexible ditopic conjugated linkers have been synthesized and characterized by electrochemistry, spectroelectrochemistry, and single crystal X-ray diffraction. The electrochemical investigations evidence that the two metallic bisdithiolene moieties are electronically coupled in the monocationic state. DFT and TDDFT calculations further suggest that the intervalence charge transfer within both monocations is essentially localized on the ligand and can be described as an intraligand charge transfer (ILCT).
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