IMN

Biblio. IMN

Référence en vue solo

Utrera-Melero, R., Mevellec, J.-Y., Gautier, N., Stephant, N., Massuyeau, F. & Perruchas, S. (2019) Aggregation-Induced Emission Properties of Copper Iodide Clusters. Chemistry-an Asian Journal, 14 3166–3172. 
Added by: Richard Baschera (2019-09-30 09:09:02)   Last edited by: Richard Baschera (2019-09-30 09:30:30)
Type de référence: Article
DOI: 10.1002/asia.201900807
Clé BibTeX: UtreraMelero2019
Voir tous les détails bibliographiques
Catégories: IMN, MIOPS
Créateurs: Gautier, Massuyeau, Mevellec, Perruchas, Stephant, Utrera-Melero
Collection: Chemistry-an Asian Journal
Consultations : 9/264
Indice de consultation : 3%
Indice de popularité : 0.75%
Résumé     
The aggregation-induced emission (AIE) properties of two different copper iodide clusters have been studied. These two [Cu4I4L4] clusters differ by their coordinated phosphine ligand and the luminescent mechanochromic properties are only displayed by one of them. The two clusters are AIE-active luminophors that exhibit an intense emission in the visible region upon aggregation. The formed particles present luminescent thermochromism comparable to that of the bulk compounds. The observed AIE properties can be attributed to suppression of nonradiative relaxation of the excited states in a more rigid state, in relation to the large structural relaxation of the excited triplet state. The differences observed in the AIE properties of the two clusters can be related to the different ligands. A correlation between the luminescence mechanochromic properties and the AIE effect is not straightforward, but the formation of "soft" molecular solids is a common characteristic that can explain the photoactive properties of these compounds.
  
wikindx 4.2.2 ©2014 | Références totales : 2608 | Requêtes métadonnées : 53 | Exécution de script : 0.11279 secs | Style : Harvard | Bibliographie : Bibliographie WIKINDX globale