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Sasaki, S., Lesault, M., Grange, E., Janod, E., Corraze, B., Cadars, S., Caldes, M. T., Guillot-Deudon, C., Jobic, S. & Cario, L. (2019) Unexplored reactivity of (S-n)(2-) oligomers with transition metals in low-temperature solid-state reactions. Chemical Communications, 55 6189–6192.
Added by: Richard Baschera (2019-07-15 14:27:14) Last edited by: Richard Baschera (2019-07-17 09:37:50) |
| Type de référence: Article DOI: 10.1039/c9cc01338e Clé BibTeX: Sasaki2019 Voir tous les détails bibliographiques  |
Catégories: IMN, MIOPS, PMN Créateurs: Cadars, Caldes, Cario, Corraze, Grange, Guillot-Deudon, Janod, Jobic, Lesault, Sasaki Collection: Chemical Communications |
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| Résumé |
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We demonstrate here the low temperature topochemical insertion of transition elements (Fe, Ni, and Cu) in precursors containing pre-formed (S-n)(2-) (n = 2 and 3) oligomers.Indeed, this soft chemistry route opens the door to the easy, orientated synthesis of low dimensional transition metal compounds provided that the elemental metal can retrocede electron(s) to empty antibonding sulfur sigma* levels.
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