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El Moll, H., Cordier, M., Nocton, G., Massuyeau, F., Latouche, C., Martineau-Corcos, C. & Perruchas, S. (2018) A Heptanuclear Copper Iodide Nanocluster. Inorganic Chemistry, 57 11961–11969. 
Added by: Richard Baschera (2018-12-19 10:00:47)   Last edited by: Richard Baschera (2018-12-19 10:04:56)
Type de référence: Article
DOI: 10.1021/acs.inorgchem.8b01516
Clé BibTeX: ElMoll2018
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Créateurs: Cordier, El Moll, Latouche, Martineau-Corcos, Massuyeau, Nocton, Perruchas
Collection: Inorganic Chemistry
Consultations : 3/286
Indice de consultation : 2%
Indice de popularité : 0.5%
Nanoscale molecular clusters are attractive for the design of materials exhibiting original functions and properties. In particular, copper iodide clusters of high nuclearity are well-known for their stimuli-responsive luminescence properties. The synthesis and characterization of an unprecedented copper(I) iodide molecular cluster based on an original heptanuclear inorganic core are reported. This nanometer-size cluster is formulated as [Cu7I7(P(C6H4CF3)(3))(6) (CH3CN)] and its novel structure has been characterized by X-ray diffraction and multinuclear solid-state Cu-63, P-31, C-13, F-19, and H-1 NMR spectroscopy. The photoluminescence properties of this cluster have been studied at variable temperature. Density functional theory calculations have been performed on this large molecular structure and allow one to rationalize the observed luminescence properties. This study highlights the crucial role of cuprophilic interactions in molecular copper iodide clusters for exhibiting photoactive properties.
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