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Abeykoon, B., Devic, T., Greneche, J.-M., Fateeva, A. & Sorokin, A. B. (2018) Confinement of Fe-Al-PMOF catalytic sites favours the formation of pyrazoline from ethyl diazoacetate with an unusual sharp increase of selectivity upon recycling. Chemical Communications, 54 10308–10311. 
Added by: Richard Baschera (2018-10-04 15:04:06)   Last edited by: Richard Baschera (2018-10-04 15:18:03)
Type de référence: Article
DOI: 10.1039/c8cc06082g
Clé BibTeX: Abeykoon2018
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Catégories: ST2E
Créateurs: Abeykoon, Devic, Fateeva, Greneche, Sorokin
Collection: Chemical Communications
Consultations : 5/272
Indice de consultation : 1%
Indice de popularité : 0.25%
Résumé     
The catalytic properties of a chemically stable iron porphyrin MOF were evaluated in a reaction with ethyl diazoacetate. In contrast to its homogeneous counterpart, an Fe-porphyrin-MOF features a different reaction pathway leading to the formation of pyrazoline due to the confinement of catalytic sites within the MOF network. Unexpectedly, a sharp increase of the selectivity from 35% (run 1) to 86% (run 5) occurs upon catalyst recycling.
  
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