IMN

Biblio. IMN

Référence en vue solo

Rouschmeyer, P., Guillou, N., Serre, C., Clavier, G., Allain, C. & Devic, T. (2018) Coordination polymers built up from an s-tetrazine derived ligand and rare-earth ions: from a sequential dimensional expansion to organic-inorganic energy transfer. Dalton Transactions, 47 10715–10720. 
Added by: Richard Baschera (2018-08-23 08:07:56)   Last edited by: Richard Baschera (2018-08-23 08:08:59)
Type de référence: Article
DOI: 10.1039/c8dt01268g
Clé BibTeX: Rouschmeyer2018
Voir tous les détails bibliographiques
Catégories: ST2E
Créateurs: Allain, Clavier, Devic, Guillou, Rouschmeyer, Serre
Collection: Dalton Transactions
Consultations : 2/500
Indice de consultation : 4%
Indice de popularité : 1%
Résumé     
Coordination polymers were prepared from a luminescent s-tetrazine ligand (OTz) and various rare-earth ions. Both the radii of the Ln ions and the synthetic conditions (especially pH) drive the formation of the product, and three crystalline phases were finally identified. Using a two-step process, it was possible to increase the dimensionality of one of these compounds from 1-D (MIL-165) to 2-D (MIL-166). The luminescence properties of these coordination polymers were studied. Whereas for Ln = La, Pr, Eu, Tb, the emission characteristic of the s-tetrazine core was observed, such emission was not detected for Ln = Nd, while the emission typical for the Nd ion was present, due to energy transfer from the tetrazine ligand to the Nd3+ ion.
  
wikindx 4.2.2 ©2014 | Références totales : 2612 | Requêtes métadonnées : 52 | Exécution de script : 0.11386 secs | Style : Harvard | Bibliographie : Bibliographie WIKINDX globale