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Mouchaham, G., Abeykoon, B., Gimenez-Marquez, M., Navalon, S., Santiago-Portillo, A., Affram, M., Guillou, N., Martineau, C., Garcia, H., Fateeva, A. & Devic, T. (2017) Adaptability of the metal(III,IV) 1,2,3-trioxobenzene rod secondary building unit for the production of chemically stable and catalytically active MOFs. Chemical Communications, 53 7661–7664.
Added by: Richard Baschera (2017-07-21 13:43:01) Last edited by: Richard Baschera (2017-07-21 13:47:37) |
| Type de référence: Article DOI: 10.1039/c7cc04215a Numéro d'identification (ISBN etc.): 1359-7345 Clé BibTeX: Mouchaham2017 Voir tous les détails bibliographiques  |
Catégories: INTERNATIONAL, ST2E Créateurs: Abeykoon, Affram, Devic, Fateeva, Garcia, Gimenez-Marquez, Guillou, Martineau, Mouchaham, Navalon, Santiago-Portillo Collection: Chemical Communications |
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The use of a 5,10,15,20-tetrakis(3,4,5-trihydroxyphenyl) porphyrin has yielded a new MOF based on M-1,2,3-trioxobenzene chains that can be made of M = Zr(IV) or RE(III) (RE = rare earth), showing a very high and limited chemical stability, respectively. The robust metallated Zr-analogue, Co-MIL-173(Zr), has proven to be a heme-like heterogeneous catalyst suitable for aerobic oxidation of hydrocarbons.
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