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Mitra, S., Cerclier, C., Berrod, Q., Ferdeghini, F., de Oliveira-Silva, R., Judeinstein, P., Le Bideau, J. & Zanotti, J.-M. (2017) Ionic Liquids Confined in Silica Ionogels: Structural, Thermal, and Dynamical Behaviors. Entropy, 19 140. 
Added by: Richard Baschera (2017-04-03 12:52:37)   Last edited by: Richard Baschera (2017-07-07 14:38:55)
Type de référence: Article
DOI: 10.3390/e19040140
Clé BibTeX: Mitra2017
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Mots-clés: confinement, ionic liquid, mobility, phase transition, quasi-elastic neutron scattering
Créateurs: Berrod, Cerclier, Ferdeghini, Judeinstein, Le Bideau, Mitra, de Oliveira-Silva, Zanotti
Collection: Entropy
Consultations : 11/380
Indice de consultation : 3%
Indice de popularité : 0.75%
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Ionogels are porous monoliths providing nanometer-scale confinement of an ionic liquid within an oxide network. Various dynamic parameters and the detailed nature of phase transitions were investigated by using a neutron scattering technique, giving smaller time and space scales compared to earlier results from other techniques. By investigating the nature of the hydrogen mean square displacement (local mobility), qualitative information on diffusion and different phase transitions were obtained. The results presented herein show similar short-time molecular dynamics between pristine ionic liquids and confined ionic liquids through residence time and diffusion coefficient values, thus, explaining in depth the good ionic conductivity of ionogels.
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