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Mayer, C. R., Dumur, F., Miomandre, F., Dumas, E., Devic, T., Fosse, C. & Secheresse, F. (2007) Facile synthesis and electrochemical properties of two trinuclear ruthenium complexes based on star-shaped terpyridine derivatives. NEW JOURNAL OF CHEMISTRY, 31 1806–1814.
Added by: Richard Baschera (2017-03-01 08:48:24) |
| Type de référence: Article Clé BibTeX: Mayer{2007} Voir tous les détails bibliographiques  |
Catégories: HORSIMN Créateurs: Devic, Dumas, Dumur, Fosse, Mayer, Miomandre, Secheresse Collection: {NEW JOURNAL OF CHEMISTRY} |
Consultations : 1/407
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| Résumé |
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{Two trinuclear ruthenium complexes {[}{TolylTerpyRu}(3)(L3A)] center dot (PF(6))(9) and {[}{TolylTerpyRu}(3)(L3B)] center dot (PF6)9 containing the star-shaped ligands l,3,5-trisJ{[}4'-(2,2':61',211terpyridinyl)- I -pyridiniumyl]methylphenyl} benzene (L3A) and 2,4,6-trisJ{[}4'-(2,2':6,2{''}terpyridinyl)-l-pyridiniumyllmethyllmesity lene (L3B), respectively, have been synthesized and characterized using electrospray ionization mass spectrometry, UV-Vis spectroscopy, lH and 13 C NMR spectroscopy. These cationic ligands have been synthesized using a 1,3,5triphenylbenzene or a mesitylene core and the N-alkylation of the 4'-pyridyl group of 4'-(4-pyridyl)-2,2':6',2{''}-terpyridine (terpy,py). The electrochemical properties of the two trinuclear ruthenium complexes have been compared to analogous dinuclear and mononuclear ruthenium complexes.
Added by: Richard Baschera |