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Devic, T., Salles, F., Bourrelly, S., Moulin, B., Maurin, G., Horcajada, P., Serre, C., Vimont, A., Lavalley, J.-C., Leclerc, H., Clet, G., Daturi, M., Llewellyn, P. L., Filinchuk, Y. & Ferey, G. (2012) Effect of the organic functionalization of flexible MOFs on the adsorption of CO2. JOURNAL OF MATERIALS CHEMISTRY, 22 10266–10273.
Added by: Richard Baschera (2017-03-01 08:48:22) |
| Type de référence: Article DOI: {10.1039/c2jm15887f} Numéro d'identification (ISBN etc.): {0959-9428} Clé BibTeX: Devic{2012} Voir tous les détails bibliographiques  |
Catégories: HORSIMN Créateurs: Bourrelly, Clet, Daturi, Devic, Ferey, Filinchuk, Horcajada, Lavalley, Leclerc, Llewellyn, Maurin, Moulin, Salles, Serre, Vimont Collection: {JOURNAL OF MATERIALS CHEMISTRY} |
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| Résumé |
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{The adsorption of CO2 by a series of functionalized flexible MIL-53(Fe) solids has been evaluated through a combination of in situ X-ray power diffraction, adsorption calorimetry, IR spectroscopy and computer modelling. It appears that (i) strongly polar groups maintain the nonporous structure in its closed form due to strong intra-framework interactions and (ii) less polar functional groups allow only a modulation of the CO2-framework interactions, in some cases with a disappearance of the initial intra-framework mu(2)-OH center dot center dot center dot X hydrogen bonds, but do not interact directly with the CO2 molecules.}
Added by: Richard Baschera |