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Dan-Hardi, M., Chevreau, H., Devic, T., Horcajada, P., Maurin, G., Ferey, G., Popov, D., Riekel, C., Wuttke, S., Lavalley, J.-C., Vimont, A., Boudewijns, T., de Vos, D. & Serre, C. (2012) How Interpenetration Ensures Rigidity and Permanent Porosity in a Highly Flexible Hybrid Solid. CHEMISTRY OF MATERIALS, 24 2486–2492. 
Added by: Richard Baschera (2017-03-01 08:48:22)
Type de référence: Article
DOI: {10.1021/cm300450x}
Numéro d'identification (ISBN etc.): {0897-4756}
Clé BibTeX: DanHardi{2012}
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Catégories: HORSIMN
Créateurs: Boudewijns, Chevreau, Dan-Hardi, Devic, Ferey, Horcajada, Lavalley, Maurin, Popov, Riekel, Serre, Vimont, de Vos, Wuttke
Consultations : 1/338
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{The synthesis and the crystal structure determination, using a synchrotron microdiffraction setup, of the interwoven analogue of the highly flexible iron(III) dicarboxylate MIL-88D structure are reported. Unlike its flexible counterpart, MIL-126, or (Fe3O)-O-III(H2O)(2)(OH)-{[}(O2C)-C12H8-(CO2)](3)center dot n(solv), exhibits a rigid structure with an accessible three dimensional (3D) pore system resulting in a Brunauer-Emmett-Teller (BET) surface area over 1700 m(2).g(-1). Moreover, a large amount of coordinatively unsaturated Fe sites of +2 and +3 oxidation states are accessible to NO and acetonitrile molecules as shown by infrared spectroscopy. MIL-126 might be thus used for the removal of aromatic N-heterocyclic compounds from fossil fuel streams, as shown here in the efficient capture of indole from model benzothiophene/indole mixtures in heptane/toluene.}
Added by: Richard Baschera  
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