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Kolokolov, D. I., Jobic, H., Stepanov, A. G., Ollivier, J., Rives, S., Maurin, G., Devic, T., Serre, C. & Ferey, G. (2012) Experimental and Simulation Evidence of a Corkscrew Motion for Benzene in the Metal-Organic Framework MIL-47. JOURNAL OF PHYSICAL CHEMISTRY C, 116 15093–15098.
Added by: Richard Baschera (2017-03-01 08:48:22) |
| Type de référence: Article DOI: {10.1021/jp302995b} Numéro d'identification (ISBN etc.): {1932-7447} Clé BibTeX: Kolokolov{2012} Voir tous les détails bibliographiques  |
Catégories: HORSIMN Créateurs: Devic, Ferey, Jobic, Kolokolov, Maurin, Ollivier, Rives, Serre, Stepanov Collection: {JOURNAL OF PHYSICAL CHEMISTRY C} |
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| Résumé |
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{Some bacteria move with a corkscrew motion, meeting less resistance from surrounding water. A spiral movement is also considered during RNA polymerase translocation and it has been observed for water and proteins. We have found that benzene molecules confined in the metal organic framework MIL-47 move in a corkscrew fashion. This spectacular diffusion effect could be put into evidence by combining experimental and computation tools; the two experimental techniques, quasielastic neutron scattering and H-2 NMR, cover a wide range of time scales.}
Added by: Richard Baschera |