Nouar, F., Breeze, M. I., Campo, B. C., Vimont, A., Clet, G., Daturi, M., Devic, T., Walton, R. I. & Serre, C. (2015) Tuning the properties of the UiO-66 metal organic framework by Ce substitution. CHEMICAL COMMUNICATIONS, 51 14458–14461.
Added by: Richard Baschera (2017-03-01 08:48:21) |
Type de référence: Article DOI: {10.1039/c5cc05072c} Numéro d'identification (ISBN etc.): {1359-7345} Clé BibTeX: Nouar{2015} Voir tous les détails bibliographiques |
Catégories: HORSIMN Créateurs: Breeze, Campo, Clet, Daturi, Devic, Nouar, Serre, Vimont, Walton Collection: {CHEMICAL COMMUNICATIONS} |
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Résumé |
{Crystallisation of a mixed-metal form of the porous framework UiO-66 in which Zr is partially replaced by Ce produces a liganddefective material, that contains some Ce(III) as well as a majority of Ce(IV). Infrared spectroscopy shows enhanced binding of methanol in the substituted material that leads to catalytic decomposition of the alcohol, which may be due to a combination of defects and redox activity.}
Added by: Richard Baschera |