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Mouchaham, G., Cooper, L., Guillou, N., Martineau, C., Elkaim, E., Bourrelly, S., Llewellyn, P. L., Allain, C., Clavier, G., Serre, C. & Devic, T. (2015) A Robust Infinite Zirconium Phenolate Building Unit to Enhance the Chemical Stability of Zr MOFs. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 54 13297–13301.
Added by: Richard Baschera (2017-03-01 08:48:21) |
| Type de référence: Article DOI: {10.1002/anie.201507058} Numéro d'identification (ISBN etc.): {1433-7851} Clé BibTeX: Mouchaham{2015} Voir tous les détails bibliographiques  |
Catégories: HORSIMN Créateurs: Allain, Bourrelly, Clavier, Cooper, Devic, Elkaim, Guillou, Llewellyn, Martineau, Mouchaham, Serre Collection: {ANGEWANDTE CHEMIE-INTERNATIONAL EDITION} |
Consultations : 4/393
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| Résumé |
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{A novel Zr-chain based MOF, namely MIL-163, was designed and successfully synthesized using a bis-1,2,3-trioxobenzene ligand. Endowed with large square-shaped channels of 12 angstrom width, it shows remarkable water uptake (ca. 0.6cm(3)g(-1) at saturating vapor pressure) and a remarkable stability in simulated physiological media, where archetypical Zr carboxylate MOFs readily degrade.}
Added by: Richard Baschera |