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Bolle, P., Serier-Brault, H., Genois, R., Faulques, E., Boulmier, A., Oms, O., Lepeltier, M., Marrot, J., Dolbecq, A., Mialane, P. & Dessapt, R. (2016) Drastic solid-state luminescence color tuning of an archetypal Ir(III) complex using polyoxometalates and its application as a vapoluminescence chemosensor. J. Mater. Chem. C, 4 11392–11395.
Added by: Richard Baschera (2017-02-02 13:56:05) Last edited by: Richard Baschera (2017-02-02 13:58:42) |
| Type de référence: Article DOI: 10.1039/c6tc04341k Numéro d'identification (ISBN etc.): 2050-7526 Clé BibTeX: Bolle2016 Voir tous les détails bibliographiques  |
Catégories: MIOPS Mots-clés: assemblies, blue, cationic iridium complexes, clusters, coordination chemistry, devices, emitting electrochemical-cells, probes Créateurs: Bolle, Boulmier, Dessapt, Dolbecq, Faulques, Genois, Lepeltier, Marrot, Mialane, Oms, Serier-Brault Collection: J. Mater. Chem. C |
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Using a straightforward one-step synthetic procedure, the solid-state phosphorescence of the archetypal [Ir-III(ppy)(2)(bpy)](+) complex has been successfully tuned from green to yellow, orange and red by its association with a series of polyoxometalates. Such new materials can exhibit remarkable vapoluminescence properties for the detection of volatile organic compounds (VOCs) even in the presence of moisture via a new polymorphous conversion mechanism.
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