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Tonkikh, A. A., Rybkovskiy, D. V., Orekhov, A. S., Chernov, A. I., Khomich, A. A., Ewels, C. P., Kauppinen, E. I., Rochal, S. B., Chuvilin, A. L. & Obraztsova, E. D. (2016) Optical properties and charge transfer effects in single-walled carbon nanotubes filled with functionalized adamantane molecules. Carbon, 109 87–97. 
Added by: Richard Baschera (2016-12-02 14:34:59)   Last edited by: Richard Baschera (2016-12-02 14:44:50)
Type de référence: Article
DOI: 10.1016/j.carbon.2016.07.053
Numéro d'identification (ISBN etc.): 0008-6223
Clé BibTeX: Tonkikh2016
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Catégories: INTERNATIONAL, PMN
Mots-clés: bundles, chains, Conductivity, encapsulation, graphene nanoribbons, iodine, raman-scattering, spectroscopy
Créateurs: Chernov, Chuvilin, Ewels, Kauppinen, Khomich, Obraztsova, Orekhov, Rochal, Rybkovskiy, Tonkikh
Collection: Carbon
Consultations : 1/450
Indice de consultation : 2%
Indice de popularité : 0.5%
Résumé     
The filling of single-walled carbon nanotube films with 1-adamantanemethanol and 1-bromoadamantane molecules was carried out by a gas-phase procedure. Optical absorption and Raman spectroscopies revealed the effects of charge transfer for samples treated with 1-bromoadamantane. Using density functional simulations we show that the charge transfer takes place when bromine is detached from the carbon cage and accepts electrons as free-standing atoms or as polybromide structures, Transmission electron microscope images confirm the presence of individual bromine atoms inside carbon nanotubes, treated with 1-bromoadamantane molecules. The observed charge transfer is, therefore, a marker of the dehalogenization reaction, a critical step in the synthesis process of narrow 1D sp(3) nanostructures. (C) 2016 Elsevier Ltd. All rights reserved.
  
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