Le Comte, A., Brousse, T. & Belanger, D. (2016) New generation of hybrid carbon/Ni(OH)(2) electrochemical capacitor using functionalized carbon electrode. J. Power Sources, 326 702–710.
Added by: Richard Baschera (2016-10-06 14:25:36) Last edited by: Richard Baschera (2016-10-07 09:15:45) |
Type de référence: Article DOI: 10.1016/j.jpowsour.2016.03.065 Numéro d'identification (ISBN etc.): 0378-7753 Clé BibTeX: LeComte2016a Voir tous les détails bibliographiques |
Catégories: INTERNATIONAL, ST2E Mots-clés: activated carbon, Asymmetric device, carbide-derived carbon, composite electrodes, electrochemical capacitor, energy-storage, Functionalized carbon, high-power supercapacitors, Hybrid device, ionic liquids, limits, Ni(OH)(2), Nickel, performance, Supercapacitor Créateurs: Belanger, Brousse, Le Comte Collection: J. Power Sources |
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Résumé |
Tailoring carbon based negative electrode by grafting electroactive 9,10-phenanthrenequinone molecules on porous carbon drastically improves the performance of a carbon/Ni(OH)(2) hybrid electrochemical capacitor. The grafted-quinone moieties add a Faradaic contribution to the double layer capacitance of carbon leading to a significant increase of the charge stored by the full devices. Good cyclability is ensured due to the strong bond between 9,10-phenanthrenequinone molecules and the carbon surface. More importantly, by increasing the total capacity, the grafting improves the energy density of the full hybrid device while maintaining fast charge/discharge kinetics and thus without affecting the power density. (C) 2016 Elsevier B.V. All rights reserved.
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