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Broeckx, L. E. E., Delaunay, W., Latouche, C., Lutz, M., Boucekkine, A., Hissler, M. & Müller, C. (2013) C-H activation of 2,4,6-triphenylphosphinine: synthesis and characterization of the first homoleptic phosphinine-iridium(III) complex fac-[Ir(C{^{}P)3].}. Inorganic Chemistry, 52 10738–10740.
Added by: Richard Baschera (2016-09-27 07:35:11) |
| Type de référence: Article DOI: 10.1021/ic401933m Numéro d'identification (ISBN etc.): 1520-510X Clé BibTeX: Broeckx2013 Voir tous les détails bibliographiques  |
Catégories: HORSIMN Créateurs: Boucekkine, Broeckx, Delaunay, Hissler, Latouche, Lutz, Müller Collection: Inorganic Chemistry |
Consultations : 1/559
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| Liens URLs http://www.ncbi.nl ... ov/pubmed/24020357 |
| Résumé |
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Access to homoleptic phosphinine-based coordination compounds of d(6) metals has so far remained elusive. We report here on the preparation and full characterization of the first homoleptic phosphinine-iridium(III) complex, obtained by C-H activation of 2,4,6-triphenylphosphinine with [Ir(acac)3]. This result opens up new perspectives for the implementation of such aromatic heterocycles in more applied research fields.
Added by: Richard Baschera |