IMN

Biblio. IMN

Référence en vue solo

Ayachi, S., Bouzakraoui, S., Hamidi, M., Bouachrine, M., Molinie, P. & Alimi, K. (2006) Prediction of electropolymerization mechanisms of two substituted phenylene: Poly-3-methoxy-toluenes (P3mt(1) and P3mt(2)). J. Appl. Polym. Sci. 100 57–64. 
Added by: Florent Boucher (2016-05-12 13:21:37)
Type de référence: Article
DOI: 10.1002/app.22640
Numéro d'identification (ISBN etc.): 0021-8995
Clé BibTeX: Ayachi2006a
Voir tous les détails bibliographiques
Catégories: IMN
Mots-clés: density-functional theory, dft, esr, polythiophene, Radical polymerization, spin density, structure-property relations, Thiophene
Créateurs: Alimi, Ayachi, Bouachrine, Bouzakraoui, Hamidi, Molinie
Collection: J. Appl. Polym. Sci.
Consultations : 11/463
Indice de consultation : 2%
Indice de popularité : 0.5%
Résumé     
P3mt(1) and P3mt(2) were electrochemically synthesized using two different electrolyte supports H2SO4 and TEABF(4), respectively. First, it was deduced from density functional theory (DFT) calculations that the electronic and steric effects govern polymerization mechanism of the radical monomers. Second, DFT combined with experimental spectroscopic analyses (ESR, Infrared, Raman, and C-13 NMR) demonstrate that H2SO4 or TEABF(4) could generate a homogenous or heterogeneous coupling site, respectively. (c) 2006 Wiley Periodicals, Inc.
Added by: Florent Boucher  
wikindx 4.2.2 ©2014 | Références totales : 2592 | Requêtes métadonnées : 60 | Exécution de script : 0.11472 secs | Style : Harvard | Bibliographie : Bibliographie WIKINDX globale