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Coue, V., Dessapt, R., Bujoli-Doeuff, M., Evain, M. & Jobic, S. (2006) Synthesis and characterization of two new photochromic organic-inorganic hybrid materials based on isopolyoxomolybdate: (HDBU)(3)(NH4)[beta-Mo8O26] center dot H2O and (HDBU)(4)[delta-Mo8O26]. J. Solid State Chem. 179 3615–3627. 
Added by: Florent Boucher (2016-05-12 13:21:36)
Type de référence: Article
DOI: 10.1016/j.jssc.2006.07.031
Numéro d'identification (ISBN etc.): 0022-4596
Clé BibTeX: Coue2006
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Catégories: MIOPS
Mots-clés: building-blocks, composite-solids, dbu, electronic-structure, gamma-octamolybdate, Hydrothermal synthesis, intervalence charge transfer, metal-complexes, Molybdenum, Molybdenum oxide, octamolybdate clusters, organic-inorganic hybrid materials, photochromism, polyoxometalates, polyoxomolybdate clusters, ray crystal-structure
Créateurs: Bujoli-Doeuff, Coue, Dessapt, Evain, Jobic
Collection: J. Solid State Chem.
Consultations : 8/375
Indice de consultation : 1%
Indice de popularité : 0.25%
Résumé     
{Two new organic-inorganic hybrid compounds of molybdenum(VI) (HDBU)(3)(NH4)[beta-Mo8O26] (.) H2O 1 and (HDBU)(4)[delta-Mo8O26] 2 have been synthesized and characterized by elemental analyses, FT-IR and UV-vis spectroscopies, and single-crystal X-ray diffraction (at 293 and 100 K. respectively). Compound I is obtained at room temperature by adding 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) on aqueous molybdate solution at pH = 5.7. Compound 2 is obtained hydrothermally from 1 (110 degrees C, 24 h, autogenous pressure). Compound I crystallizes in the triclinic crystal system, space group P1, with a = 11.2492(9)
Added by: Florent Boucher  
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