Benamira, M., Letilly, M., Quarez, E., Joubert, O. & La Salle, L. G. A. (2014) Optimization of SOFC anode/electrolyte assembly based on BaIn0.3Ti0.7O2.85 (BIT07)/Ni-BIT07 using an interfacial anodic layer. J. Power Sources, 251 66–74.
Added by: Florent Boucher (2016-04-29 09:26:44) |
Type de référence: Article DOI: 10.1016/j.jpowsour.2013.11.026 Numéro d'identification (ISBN etc.): 0378-7753 Clé BibTeX: Benamira2014a Voir tous les détails bibliographiques |
Catégories: ST2E Mots-clés: Anode active layer, BaIn0.3Ti0.7O2.85(BIT07)(BIT07) for SOFC, cermet, Co-sintering, eis, electrolyte, gas, Impedance, Ni current collector, oxide fuel-cells, performance, Tape casting, temperature Créateurs: Benamira, Joubert, La Salle, Letilly, Quarez Collection: J. Power Sources |
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Résumé |
BaIn0.3Ti0.7O2.85 (BIT07) is a potential electrolyte material for Solid Oxide Fuel Cells (SOFCs) due to its high ionic conductivity and its compatibility with commonly used cathode materials. By using tape casting and co-sintering shaping methods symmetrical cells BIT07-Ni/BIT07/BIT07-Ni have been prepared. In order to improve the interface between BIT07-Ni and BIT07, a thin anode functional active layer (AAL) deposited between the BIT07-Ni and BITO7 is used. The effect of this layer on the electrochemical performance of the symmetrical cells as well as the influence of an additional Ni current collecting layer deposited on the anode side are discussed in this study. It is shown that the presence of the AAL decreases the area specific resistance (ASR) of the anode/assembly by a factor of about two, and that the presence of the Ni layer slows down the ageing of the assembly. (C) 2013 Elsevier B.V. All rights reserved.
Added by: Florent Boucher |