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Saad, A., Rousseau, G., El Moll, H., Oms, O., Mialane, P., Marrot, J., Parent, L., Mbomekalle, I.-M., Dessapt, R. & Dolbecq, A. (2014) Molybdenum Bisphosphonates with Cr(III) or Mn(III) Ions. J. Clust. Sci. 25 795–809. 
Added by: Florent Boucher (2016-04-29 09:26:44)
Type de référence: Article
DOI: 10.1007/s10876-013-0655-3
Numéro d'identification (ISBN etc.): 1040-7278
Clé BibTeX: Saad2014
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Catégories: MIOPS
Mots-clés: behavior, Bisphosphonate, Chromium, Cocrystallization, complexes, crystal-structure, diphosphonates, electrochemistry, heteropolyanions, ligands, Molybdenum, polyoxometalate, polyoxomolybdates, reduction, solid-state
Créateurs: Dessapt, Dolbecq, El Moll, Marrot, Mbomekalle, Mialane, Oms, Parent, Rousseau, Saad
Collection: J. Clust. Sci.
Consultations : 6/362
Indice de consultation : 1%
Indice de popularité : 0.25%
The synthesis of Mo-VI bisphosphonates (BPs) complexes in the presence of a heterometallic element has been studied. Two different BPs have been used, the alendronate ligand, [O3PC(C3H6NH3)(O)PO3](4-) (Ale) and a new BP derivative with a pyridine ring linked to the amino group, [O3PC(C3H6NH2CH2C5H4N)(O)PO3](4-) (AlePy). Three compounds have been isolated, a tetranuclear Mo-VI complex with Cr-III ions, (NH4)(5)[(Mo2O6)(2)(O3PC(C3H6NH3)(O)PO3)(2)Cr]center dot 11H(2)O (Mo-4(Ale)(2)Cr), its Mn-III analogue, (NH4)(4.5)Na-0.5[(Mo2O6)(2)(O3PC(C3H6NH3)(O)PO3)(2)Mn]center dot 9H(2)O (Mo-4(Ale)(2)Mn), and a cocrystal of two polyoxomolybdates, (NH4)(10)Na-3[(Mo2O6)(2)(O3PC(C3H6NH2CH2C5H4N)(O)PO3)(2)Cr](2)[CrMo6(OH)(6)O-18]center dot 37H(2)O ([Mo-4(AlePy)(2)Cr](2)[CrMo6]). In this latter compound an Anderson-type POM [CrMo6(OH)(6)O-18](3-) is sandwiched between two tetranuclear Mo-VI complexes with AlePy ligands. The protonated triply bridging oxygen atoms bound to the central Cr-III ion of the Anderson anion develop strong hydrogen bonding interactions with the oxygen atoms of the bisphosphonate complexes. The UV-Vis spectra confirm the coexistence in solution of both POMs. Cyclic voltammetry experiments have been performed, showing the reduction of the Mo centers. In strong contrast with the reported Mo-VI BP systems, the presence of trivalent cations in close proximity to the Mo-VI centers dramatically impact the potential solid-state photochromic properties of these compounds.
Added by: Florent Boucher  
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