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Arcon, D., Pregelj, M., Cevc, P., Rotas, G., Pagona, G., Tagmatarchis, N. & Ewels, C. (2007) Stability, thermal homolysis and intermediate phases of solid hydroazafullerene C59HN. Chem. Commun. 3386–3388.
Added by: Laurent Cournède (2016-03-10 22:02:31) |
| Type de référence: Article DOI: 10.1039/b703766j Numéro d'identification (ISBN etc.): 1359-7345 Clé BibTeX: Arcon2007 Voir tous les détails bibliographiques  |
Catégories: PMN Mots-clés: azafullerene (c59n)(2), esr Créateurs: Arcon, Cevc, Ewels, Pagona, Pregelj, Rotas, Tagmatarchis Collection: Chem. Commun. |
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| Résumé |
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Density functional (DFT) calculations, high-temperature electron paramagnetic resonance (EPR) and transmission electron microscopy (TEM) results suggest that thermal homolysis of C59HN involves a remarkably stable intermediate C59N-C59HN center dot structure characterised by charge redistribution from a C59N center dot radical to a bonded C59HN.
Added by: Laurent Cournède |