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Dupre, N., Martin, J.-F., Oliveri, J., Soudan, P., Guyomard, D., Yamada, A. & Kanno, R. (2009) Aging of the LiNi1/2Mn1/2O2 Positive Electrode Interface in Electrolyte. J. Electrochem. Soc. 156 C180–C185.
Added by: Laurent Cournède (2016-03-10 21:41:25) |
| Type de référence: Article DOI: 10.1149/1.3098494 Numéro d'identification (ISBN etc.): 0013-4651 Clé BibTeX: Dupre2009a Voir tous les détails bibliographiques  |
Catégories: ST2E Mots-clés: Cathode material, electrochemical-behavior, Li-ion batteries, lithium, MAS NMR, solid-solution, surface-chemistry, thin-films, ultrahigh-vacuum, x-ray-diffraction Créateurs: Dupre, Guyomard, Kanno, Martin, Oliveri, Soudan, Yamada Collection: J. Electrochem. Soc. |
Consultations : 18/910
Indice de consultation : 5% Indice de popularité : 1.25% |
| Résumé |
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The evolution of lithium-containing species on the surface of grains of layered LiNi1/2Mn1/2O2 material during the aging process in LiPF6 (ethylene carbonate/dimethyl carbonate, 1 M) electrolyte has been followed using Li-7 magic angle spinning NMR spectroscopy. Materials displaying different surface areas have been investigated in order to study the influence of the surface/volume ratio. The evolution of the NMR signal shows that the reaction of the active material with the electrolyte is extremely fast during the first moments of exposure and tends to slow down for longer exposure times. Coupled NMR, electrochemical impedance spectroscopy, and transmission electron microscopy experiments showed that the surface of the material grains is not covered by a homogeneous layer, indicating that the reaction with electrolyte cannot be considered as a real passivation reaction. The aging process performed on a sample initially stored in ambient atmosphere clearly demonstrates the dissolution of a pristine Li2CO3 surface layer and the growth of an interphase made primarily of fluorinated compounds. (C) 2009 The Electrochemical Society. [DOI: 10.1149/1.3098494] All rights reserved.
Added by: Laurent Cournède |