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Osuna, S., Torrent-Sucarrat, M., Sola, M., Geerlings, P., Ewels, C. P. & Van Lier, G. (2010) Reaction Mechanisms for Graphene and Carbon Nanotube Fluorination. J. Phys. Chem. C, 114 3340–3345. 
Added by: Laurent Cournède (2016-03-10 21:37:33)
Type de référence: Article
DOI: 10.1021/jp908887n
Numéro d'identification (ISBN etc.): 1932-7447
Clé BibTeX: Osuna2010
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Catégories: PMN
Mots-clés: de-fluorination, density, eels characterization, energies, fluorides, Fullerenes, nanofibers, nanoteflons, sidewall functionalization, spectroscopy
Créateurs: Ewels, Geerlings, Osuna, Sola, Torrent-Sucarrat, Van Lier
Collection: J. Phys. Chem. C
Consultations : 1/654
Indice de consultation : 3%
Indice de popularité : 0.75%
Résumé     
Via density functional theory calculations, we explore the process of graphene and carbon nanotube fluorination. Contrary to graphene, HF-catalyzed carbon nanotube fluorination adds fluorine pairs at (1,4) spacing, naturally leading to a self-organized C4F coverage, which call subsequently rearrange into dense axial C2F lines by fluorine diffusion upon solubilization or heat treatment. Controlling the fluorination process and subsequent nanotube processing results in fluorinated material types with unexplored electronic and chemical properties.
Added by: Laurent Cournède  
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