Lefort, R., Duvail, J. .-L., Corre, T., Zhao, Y. & Morineau, D. (2011) Phase separation of a binary liquid in anodic aluminium oxide templates. Eur. Phys. J. E, 34 71.
Added by: Laurent Cournède (2016-03-10 21:32:20) |
Type de référence: Article DOI: 10.1140/epje/i2011-11071-2 Numéro d'identification (ISBN etc.): 1292-8941 Clé BibTeX: Lefort2011 Voir tous les détails bibliographiques |
Catégories: PMN Mots-clés: confinement, fluid mixture, local-structure, neutron-scattering, pores, porous-medium, systems, triethylamine, Water Créateurs: Corre, Duvail, Lefort, Morineau, Zhao Collection: Eur. Phys. J. E |
Consultations : 1/548
Indice de consultation : 4% Indice de popularité : 1% |
Résumé |
The radial nanostructure of the binary liquid triethylamine/water confined in 60nm diameter independent cylindrical pores of anodic aluminium oxide membranes is studied by small angle neutron scattering. It is shown that composition inhomogeneities are present in the confined mixtures well below the bulk critical point. An analysis of the neutron scattering form factor reveals the existence of an adsorbed water layer of a few nanometers at the liquid/alumina interface, coexisting with a TEA-rich phase in the core.
Added by: Laurent Cournède |