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Marko, H., Arzel, L., Darga, A., Barreau, N., Noel, S., Mencaraglia, D. & Kessler, J. (2011) Influence of Cu off-stoichiometry on wide band gap CIGSe solar cells. Thin Solid Films, 519 7228–7231. 
Added by: Laurent Cournède (2016-03-10 21:32:20)
Type de référence: Article
DOI: 10.1016/j.tsf.2010.12.174
Numéro d'identification (ISBN etc.): 0040-6090
Clé BibTeX: Marko2011
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Catégories: CESES
Mots-clés: cu(in, cuinse2, Ga)Se(2), Off-stoichiometry tolerance, Thin film solar cells, Wide bandgap
Créateurs: Arzel, Barreau, Darga, Kessler, Marko, Mencaraglia, Noel
Collection: Thin Solid Films
Consultations : 13/319
Indice de consultation : 2%
Indice de popularité : 0.5%
The electric properties of solar cells based on co-evaporated Cu(In,Ga)Se(2) (CIGSe) thin film show a good tolerance regarding the absorber Cu content (y = [Cu]/([In] + [Ga])) for standard Ga concentration, i.e. x = [Ga]/([In] + [Ga]) similar to 0.3. In the present contribution, we show that this tolerance is lost when the gallium content is increased. Wide bandgap CIGSe samples (x similar to 0.55) with a variation in y from 0.97 to 0.84 have been grown. The efficiency of the cells decreases from 12.6\% to 6.5\% for y = 0.97 and 0.84 respectively. For the lowest y, the efficiency is harmed because of a low short-circuit current density (J(sc)), an increased voltage dependency in the current collection, which affects the fill factor (FF), and a decrease of the open-circuit voltage (V(oc)). For y = 0.97 and 0.84 respectively, the decrease of the activation energy (E(a)) from 1.36 to 1.24 eV indicates a shift of the area of the dominant recombination from the space charge region towards the interface. There seems to be evidence that reducing the Cu-content in the CIGSe thin film will cause a decrease in the width of the space charge region. Solar cells based on Cu-rich CIGSe (1.03 {<} y {<} 1.09) have also been fabricated and characterized. A strong deterioration of their electrical properties is observed despite the KCN etch of the segregated Cu(2-x)Se binary phases at the surface, suggesting the presence of residual Cu(2-x)Se precipitates within the layer. (C) 2010 Elsevier ay. All rights reserved.
Added by: Laurent Cournède  
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