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Choubrac, L., Lafond, A., Guillot-Deudon, C., Moelo, Y. & Jobic, S. (2012) Structure Flexibility of the Cu2ZnSnS4 Absorber in Low-Cost Photovoltaic Cells: From the Stoichiometric to the Copper-Poor Compounds. Inorg. Chem. 51 3346–3348. 
Added by: Laurent Cournède (2016-03-10 21:28:39)
Type de référence: Article
DOI: 10.1021/ic202569q
Numéro d'identification (ISBN etc.): 0020-1669
Clé BibTeX: Choubrac2012
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Catégories: MIOPS
Mots-clés: bond-valence parameters, series, stannite
Créateurs: Choubrac, Guillot-Deudon, Jobic, Lafond, Moelo
Collection: Inorg. Chem.
Consultations : 11/440
Indice de consultation : 2%
Indice de popularité : 0.5%
Résumé     
{Here we present for the very first time a single-crystal investigation of the Cu-poor Zn-rich derivative of Cu2ZnSnS4. Nowadays, this composition is considered as the one that delivers the best photovoltaic performances in the specific domain of Cu2ZnSnS4-based thin-film solar cells. The existence of this nonstoichiometric phase is definitely demonstrated here in an explicit and unequivocal manner on the basis of powder and single-crystal X-ray diffraction analyses coupled with electron microprobe analyses. Crystals are tetragonal, space group I (4) over bar4
Added by: Laurent Cournède  
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